Author/Authors :
Joji Ohshita، نويسنده , , Hidekazu Arase، نويسنده , , Tomohisa Sumida، نويسنده , , Nobuhisa Mimura، نويسنده , , Kazuhiro Yoshimoto، نويسنده , , Yosuke Tada، نويسنده , , Yoshihito Kunugi، نويسنده , , Yutaka Harima، نويسنده , , Atsutaka Kunai، نويسنده ,
Abstract :
UV irradiation of poly(organosilanylene-2,5-diethynylenesiloles) in benzene with an excess of Fe(CO)5 led to the formation of Fe(CO)3-coordinated silole units in the polymer backbone. The Fe(CO)3-coordinated polymers exhibited suppressed π-conjugation, relative to the parent non-coordinated polymers. Hole-transporting properties of poly(organosilanylene-2,5-diethynylenesiloles) were examined by the performance of EL devices containing the polymer layer as the hole-transport and Alq3 layer as the electron-transporting emitter.
Keywords :
Silole , Iron carbonyl complex , Hole transport , EL device , Silicon polymer
