Title of article :
Synthesis of cyclopentadienyl gadolinium and samarium alkoxide complexes
Author/Authors :
Sherrika D. Daniel، نويسنده , , Jean-Sébastien M. Lehn، نويسنده , , Paul van der Heide، نويسنده , , Yongqiang Wang، نويسنده , , David M. Hoffman، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2006
Abstract :
The mixed ligand complexes [{Gd(OCMe2-i-Pr)2Cp}2], [{Sm(OCMe2-i-Pr)2Cp}2], and [Sm2(OCMe2-i-Pr)3Cp3] were synthesized by reacting [LnCp3] with HOCMe2-i-Pr. X-ray crystallographic studies show that the three complexes each have two bridging alkoxide ligands linking two metal atoms. The coordination geometries at the metals are distorted tetrahedral.
Keywords :
Gadolinium , Alkoxide , Gadolinium oxide films , Samarium , Cyclopentadienyl
Journal title :
INORGANICA CHIMICA ACTA
Journal title :
INORGANICA CHIMICA ACTA
