Title of article :
Octahedral rhenium cluster complexes with organic ligands: Synthesis, structure and properties of [Re6Q8(3,5-Me2PzH)6]Br2 · 2(3,5-Me2PzH) (Q = S, Se)
Author/Authors :
Yuri V. Mironov، نويسنده , , Konstantin A. Brylev، نويسنده , , Michael A. Shestopalov، نويسنده , , Spartak S. Yarovoi، نويسنده , , Vladimir E. Fedorov، نويسنده , , Hartmut Spies، نويسنده , , Hans-Juergen Pietzsch، نويسنده , , Holger Stephan، نويسنده , , Gerhard Geipel، نويسنده , , Gert Bernhard، نويسنده , , Werner Kraus، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2006
Abstract :
Two new octahedral cluster complexes – [Re6S8(3,5-Me2PzH)6]Br2 · 2(3,5-Me2PzH) (1) and [Re6Se8(3,5-Me2PzH)6]Br2 · 2(3,5-Me2PzH) (2), where 3,5-Me2PzH is 3,5-dimethylpyrazole, have been synthesized using reaction of rhenium chalcobromide complexes Cs4[Re6S8Br6] · 2H2O and Cs3[Re6Se8Br6] · H2O, respectively, with molten 3,5-dimethylpyrazole. Both compounds synthesized were characterized by X-ray single-crystal diffraction and chemical analysis, IR and luminescent spectra.
Keywords :
Organic ligands , crystal structure , Octahedral clusters , Rhenium complexes , Synthesis
Journal title :
INORGANICA CHIMICA ACTA
Journal title :
INORGANICA CHIMICA ACTA
