Title of article
Synthesis, characterisation and reactivity of oxodiperoxo-[2-(1-pyrazolyl)-6-menthylpyridine]molybdenum(VI): The first chiral 2-(1-pyrazole)pyridineoxodiperoxomolybdenum(VI) complex
Author/Authors
Elisabete da Palma Carreiro، نويسنده , , Guo Yong-En، نويسنده , , Anthony J. Burke، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
5
From page
1519
To page
1523
Abstract
We have obtained a novel chiral enantiomerically pure molybdenum complex of the type MoO(O2)2LL′ which has been fully characterised, including structural determination by X-ray crystallography and screened in a series of epoxidation reactions with simple olefins giving satisfactory conversions, but low enantioselectivities. It’s mode of epoxidation has been investigated.
Keywords
Pyridine–pyrazole ligand , Oxodiperoxomolybdenum(VI) complex , Asymmetric catalysis , Epoxidation
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2006
Journal title
INORGANICA CHIMICA ACTA
Record number
1323502
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