• Title of article

    Unprecedented quadruple Me2biim-bridged di- and tetranuclear complexes: Syntheses, structures and magnetic properties

  • Author/Authors

    Rui-Li Sang، نويسنده , , Li Xu، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2006
  • Pages
    6
  • From page
    2337
  • To page
    2342
  • Abstract
    Quadruple Me2biim-bridged di- and tetranuclear complexes[Cu2(H2O)2(Me2biim)4](SO4)2 (1) and [Cr4(μ-Cl)(μ-Me2biim)8(H2O)1.67(OH)0.33](ClO4)6.67 (2) have been prepared and characterized. The repulsion between the methyl groups forces the two imidazole rings out of coplanarity, responsible for the much weaker magnetic exchange coupling between the Cu2+ ions in 1.
  • Keywords
    Chromium , Biimidazole , Dinuclear complex , crystal structures , copper
  • Journal title
    INORGANICA CHIMICA ACTA
  • Serial Year
    2006
  • Journal title
    INORGANICA CHIMICA ACTA
  • Record number

    1323614

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1323614