Title of article :
A new Keggin-templated heterometal-oxide-based organic–inorganic hybrid compound
Author/Authors :
Dai، نويسنده , , Limei and You، نويسنده , , Wansheng and Li، نويسنده , , Yangguang and Liu، نويسنده , , Lihong and Ge، نويسنده , , Xiulan and Che، نويسنده , , Wenshi، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2014
Abstract :
A new Keggin-ion-templated, heterometal-oxide-based organic–inorganic hybrid compound 1 [H+]4[MnIV(bpy)2MnII(bpy)2Mo(bpy)O5]2[bpy]2[PMo11VO40]2·4H2O (bpy = 2,2′-bipyridine) has been hydrothermally synthesized and characterized by elemental analysis, IR spectroscopy, TG analysis, XPS spectrum and single-crystal X-ray diffraction. The cationic host of compound 1 represents Z-shaped hexa-metal chain of overall formula [Mn4Mo2O10(bipy)10]4+ incorporating manganese in both the +II and +IV oxidation states. The electrochemical and magnetic properties of compound 1 were also investigated.
Keywords :
Polyoxometalate , organic–inorganic hybrid , Electrochemistry , Manganese–molybdenum bimetal , magnetism
Journal title :
INORGANICA CHIMICA ACTA
Journal title :
INORGANICA CHIMICA ACTA
