Title of article
Tetrahedrally coordinated lithium(I) and zinc(II) carboxylate-phosphinates based on tetradentate 2-carboxyethyl(phenyl)phosphinate ligand
Author/Authors
Zhao، نويسنده , , Ying-Ping and Zhang، نويسنده , , Jian-Wei and Zhao، نويسنده , , Cui-Cui and Du، نويسنده , , Zi-Yi، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2014
Pages
6
From page
121
To page
126
Abstract
The reactions of lithium(I) or zinc(II) ion with 2-carboxyethyl(phenyl)phosphinic acid (H2L) afforded two tetrahedrally coordinated metal carboxylate-phosphonites, namely, [Li(HL)] (1) and [Zn(L)] (2), which crystallize in the space groups C2/c and R-3, respectively. Compound 1 shows a double-layer structure while compound 2 features a high-symmetric three-dimensional network. The latter compound has a high thermal stability as well as a strong blue fluorescent emission.
Keywords
lithium , Phosphinates , Zinc , crystal structures
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2014
Journal title
INORGANICA CHIMICA ACTA
Record number
1323794
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