Crystal structures of the dimeric cobalt compounds [Co(PPhMe2)(CO)3]2 and [Co2(PPhMe2)3(CO)5]

The molecular structures of the dimeric cobalt compounds [Co(PPhMe2)(CO)3]2 and [Co2(PPhMe2)3(CO)5] have been characterised by X-ray crystallography. The compound [Co2(PPhMe2)3(CO)5] contains both bridging and terminal carbonyl groups in the solid state.