Title of article :
Secondary coordination of dichlorodioxomolybdenum(VI) to crown ethers
Author/Authors :
William Levason، نويسنده , , Raju Ratnani، نويسنده , , Gillian Reid، نويسنده , , L. Michael Webster، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2006
Abstract :
The reactions of MoO2Cl2 with 15-crown-5 and 18-crown-6 in ether solution produced crystals of [MoO2Cl2(H2O)2] · (15-crown-5) and [MoO2Cl2(H2O)2] · (H2O)2 · (18-crown-6) due to adventitious water. Further hydrolysis lead to crystals of [(H3O) · (crown)]2[Mo6O19]. The structures of the three complexes are briefly discussed.
Keywords :
Molybdenum , Crown ether , crystal structure , Isopolyanions
Journal title :
INORGANICA CHIMICA ACTA
Journal title :
INORGANICA CHIMICA ACTA
