Title of article
Excited state properties of Tl2B12H12. Metal-centered photoluminescence
Author/Authors
Horst Kunkely، نويسنده , , Arnd Vogler، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2007
Pages
2
From page
679
To page
680
Abstract
The compound Tl2B12H12 which consists of icosahedral View the MathML sourceB12H122- anions and Tl+ cations shows a metal-centered r.t. luminescence at λ max = 530 nm which originates from the lowest-energy sp triplet of Tl+. This emission indicates a considerable covalent interaction between Tl+ and View the MathML sourceB12H122- which is based on the hydridic nature of the boron cluster.
Keywords
Thallium , Electronic spectra , Metal-centered excited states , Photoluminescence , Phosphorescence , Borane
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2007
Journal title
INORGANICA CHIMICA ACTA
Record number
1324399
Link To Document