Title of article :
Formation of unusual ruthenium(III) carbonyl complex through ONS tricoordination of salicylaldehyde-N-phenylthiosemicarbazone
Author/Authors :
Rathinasabapathi Prabhakaran، نويسنده , , Rui Huang، نويسنده , , Ramasamy Karvembu، نويسنده , , Chinnasamy Jayabalakrishnan، نويسنده , , Karuppannan Natarajan، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2007
Abstract :
An unusual coordination mode of salicylaldehyde-N-phenylthiosemicarbazone (H2-Sal-Ptsc) ligand was observed in unusual ruthenium(III) carbonyl complex for the first time when it was reacted with [RuHCl(CO)(PPh3)3]. The EPR and electrochemical analysis conformed the formation of Ru(III) species.
Keywords :
Ruthenium(III) carbonyl complex , EPR , Cyclic voltammetry , X-ray single crystal
Journal title :
INORGANICA CHIMICA ACTA
Journal title :
INORGANICA CHIMICA ACTA
