Title of article :
Reactions of the borole complex CpRh(η5-C4H4BPh) with monocationic organometallic fragments
Author/Authors :
Loginov، نويسنده , , Dmitry A. and Muratov، نويسنده , , Dmitry V. and Perekalin، نويسنده , , Dmitry S. and Starikova، نويسنده , , Zoya A. and Petrovskaya، نويسنده , , Elena A. and Gutsul، نويسنده , , Evgenii I. and Kudinov، نويسنده , , Alexander R.، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2008
Abstract :
The B-phenylborole complex CpRh(η5-C4H4BPh) (1) reacts with [ML]+ fragments to give the arene-type cationic complexes [CpRh(μ-η5:η6-C4H4BPh)ML]+ (ML = RuCp∗ (3), Co(C4Me4) (4), Rh(cod) (5), and Ir(cod) (6)). Cation 4 undergoes a reversible rearrangement into the triple-decker complex [CpRh(μ-η5:η5-C4H4BPh)Co(C4Me4)]+ (7) under visible light irradiation in CH2Cl2 solution. DFT calculations revealed greater stability of arene-type complexes over triple-decker isomers. The structure of [3]BF4 was determined by X-ray diffraction.
Keywords :
iridium , Rhodium , Sandwich compounds , Ruthenium , boron , Boron heterocycles , Cobalt
Journal title :
INORGANICA CHIMICA ACTA
Journal title :
INORGANICA CHIMICA ACTA
