Author/Authors :
Gonzلlez، نويسنده , , Ricardo and Barboza، نويسنده , , Natalia and Chiozzone، نويسنده , , Raْl and Kremer، نويسنده , , Carlos and Armentano، نويسنده , , Donatella and De Munno، نويسنده , , Giovanni and Faus، نويسنده , , Juan، نويسنده ,
Abstract :
The linkage isomers [Re(NCS)6]2− and [Re(NCS)5(SCN)]2− are obtained by the reaction of [ReBr6]2− with NCS− in dimethylformamide. Some differences in the chemical behavior allowed their separation and structural characterization in the form of (NBu4)2[Re(NCS)6] (1) and [Zn(NO3)(Me2phen)2]2[Re(NCS)5(SCN)] (2), respectively (Bu = n-C4H9 and Me2phen = 2,9-dimethyl-1,10-phenanthroline).
Keywords :
Thiocyanate , Linkage isomerism , crystal structures , Rhenium(IV) complexes
