Title of article
Facile one-pot mono-dealkylation of H-phosphonate esters in high yield
Author/Authors
David E. Bryant، نويسنده , , Colin Kilner، نويسنده , , Terence P. Kee، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2009
Pages
3
From page
614
To page
616
Abstract
The readily available dialkyl H-phosphonates (RO)2P(O)H, where R = Me, Et, iPr, nBu and Bn can be mono-dealkylated by heating at reflux in excess tert-butylamine. Where R = Me or Bn then crystals of [(CH3)3CNH3]+ [ROP(O)HO]− form in the reaction vessel on overnight standing.
Keywords
dealkylation , Phosphonate esters , Amines
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2009
Journal title
INORGANICA CHIMICA ACTA
Record number
1326690
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