Title of article :
A copper(II) coordination polymer with alternating double EO-azido bridges and mixed EO-azido/alkoxo double bridges
Author/Authors :
Cai-Ming Liu، نويسنده , , Deqing Zhang، نويسنده , , Daoben Zhu، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2009
Abstract :
A new one-dimensional (1D) copper(II) complex, [Cu2(dpk · CH2O)(N3)3]n (dpk · CH2OH = unimethylated diol of di-2-pyridyl ketone) (1), has been synthesized and characterized. X-ray crystal structure study reveals that 1 is composed of 1D copper(II) chain with alternating double EO-azido bridges and mixed EO-azido/alkoxo double bridges. The magnetic determination indicates that ferromagnetic interaction dominates in this new 1D S = 1/2 system.
Keywords :
Di-2-pyridyl ketone complex , Copper(II) complex , Coordination polymer , Magnetic property , crystal structure , Azido ligand
Journal title :
INORGANICA CHIMICA ACTA
Journal title :
INORGANICA CHIMICA ACTA
