Title of article :
Ruthenium(VI) and osmium(VI) nitrido complexes with halogenated phenoxide and thiophenoxide ligands
Author/Authors :
Ngai-Man Lam، نويسنده , , Xiao-Yi Yi، نويسنده , , Chun-Sing Lai، نويسنده , , Wai-Man Cheung، نويسنده , , Qian-Feng Zhang، نويسنده , , Ian D. Williams، نويسنده , , Wa-Hung Leung، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2009
Abstract :
Treatment of [Bun4N][Ru(N)Cl4] with Na(OR) afforded [Bun4N][Ru(N)(OR)4] (R = C6F5 (1), C6F4H (2), C6Br5 (3)), whereas that with [Bun4N][Os(N)Cl4] gave [Bun4N][Os(N)(OR)3Cl] (R = C6F5 (4), C6F4H (5), C6Br5 (6)). Treatment of [Bun4N][M(N)Cl4] with Na(SC6F4H) and Na(Sxyl) (xyl = 2,6-dimethylphenyl) afforded [Bun4N][M(N)(SC6F4H)4] (M = Ru (7), Os (8)) and [Bun4N][M(N)(Sxyl)4] (M = Ru (9), Os (10)), respectively. The crystal structures of compounds 1, 6 and 9 have been determined.
Keywords :
Thiophenoxide , Osmium , Ruthenium , Phenoxide , Nitrido
Journal title :
INORGANICA CHIMICA ACTA
Journal title :
INORGANICA CHIMICA ACTA
