Author/Authors :
Jones، نويسنده , , Michael W. and Adlington، نويسنده , , Robert M. and Baldwin، نويسنده , , Jack E. and Le Pevelen، نويسنده , , Delphine D. and Smiljanic، نويسنده , , Nicolas، نويسنده ,
Abstract :
Three new palladium(II) complexes incorporating the bispyrazolylmethane core have been synthesised and fully characterised in the solution and solid state. Single crystal X-ray studies revealed almost complete blocking of the upper face of the palladium ion by the substituents at the 3- and 5-positions of the pyrazole rings. Preliminary screening of the complexes for palladium(II) mediated catalysis revealed good catalytic activity for the Heck coupling reaction.
