Title of article :
A simple Ru catalyst for the conversion of aldehydes or oximes to primary amides
Author/Authors :
Hull، نويسنده , , Jonathan F. and Hilton، نويسنده , , Sheena T. and Crabtree، نويسنده , , Robert H.، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2010
Abstract :
Ru(DMSO)4Cl2 is catalytically active for converting aldehydes to primary amides via oxime intermediates. This catalyst is readily available, and requires no additional ligands, a great simplification compared to previous work. A Ru(II)/(IV) mechanism is proposed.
Keywords :
Beckmann rearrangement , Aldoxime
Journal title :
INORGANICA CHIMICA ACTA
Journal title :
INORGANICA CHIMICA ACTA
