Title of article
Dinuclear Rh(II) complexes with one polypyridyl ligand, structure, properties and antitumor activity
Author/Authors
?wikowska، نويسنده , , Magdalena and Pruchnik، نويسنده , , Florian P. and Starosta، نويسنده , , Rados?aw and Chojnacki، نويسنده , , Henryk and Wilczok، نويسنده , , Adam and U?aszewski، نويسنده , , Stanis?aw، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2010
Pages
8
From page
2401
To page
2408
Abstract
Rhodium(II) complexes [Rh2(μ-OAc)2(OAc)(bpy)(H2O)2]PF6 (1), [Rh2(μ-OAc)2(OAc)(phen)(H2O)2](PF6)·H2O (2), [Rh2(μ-OOCCH3)3(OOCCH3)(phen)] (3) and [Rh2(μ-O2CCH3)3(O2CCH3)(Ph2phen)] (4) (Ph2phen = 4,7-diphenyl-1,10-phenanthroline) have been synthesized and characterized by means of NMR, IR and UV–Vis spectroscopic methods. X-ray structure of complex 4·1.5(CH3COCH3) has been determined and its geometry and electronic structure has been elucidated using OPBE and B3LYP DFT methods. The compounds are active cytostatic agents against tumor cells.
Keywords
Rhodium(II) , Antitumor activity , Dinuclear rhodium complexes , UV–vis spectra , DFT calculation , Polypyridyls
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2010
Journal title
INORGANICA CHIMICA ACTA
Record number
1328496
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