Title of article :
Halo-complexes of titanium(III): The thermochromic behaviour of [NBu4][TiCl4(THF)2]
Author/Authors :
Biagini، نويسنده , , Paolo and Bonoldi، نويسنده , , Lucia and Marchetti، نويسنده , , Fabio and Pampaloni، نويسنده , , Guido، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2010
Abstract :
TiCl3(thf)3 reacts with ACl (A = NBu4, PPN; PPN = Ph3PNPPh3) in dichloromethane solution, affording the compounds A[TiCl4(thf)2] (A = NBu4, 1; A = PPN, 2). Compound 1, dissolved in CH2Cl2, exhibits thermochromic behaviour which has been the subject of variable-temperature UV–Vis investigations.
Keywords :
UV–VIS , chloride , Thermochromism , ion pairs , Titanium(III)
Journal title :
INORGANICA CHIMICA ACTA
Journal title :
INORGANICA CHIMICA ACTA
