Title of article
Nickel(II) complexes of di- and tri-substituted thiourea mono- and di-anions
Author/Authors
Yuen، نويسنده , , Ho Ying and Henderson، نويسنده , , William and Oliver، نويسنده , , Allen G.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2011
Pages
5
From page
1
To page
5
Abstract
Reaction of nickel(II) acetate, 1,2-bis(diphenylphosphino)ethane (dppe), and a di- or tri-substituted thiourea R1NHC(S)R2R3 (R3 = H or alkyl) with trimethylamine in hot methanol gave cationic nickel(II) complexes containing N,S-chelated thiourea monoanion ligands [Ni{SC(NR2R3)NR1}(dppe)]+, which can be readily isolated as their BPh4− salts. The X-ray crystal structure of [Ni{SC(NMe2)NPh}(dppe)]+BPh4− is reported.
Keywords
Nickel complexes , Thiourea complexes , Sulfur donor ligands , crystal structure
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2011
Journal title
INORGANICA CHIMICA ACTA
Record number
1329515
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