Title of article
Intermetallic coinage metal-catalyzed functionalization of alkanes with ethyl diazoacetate: Gold as a ligand
Author/Authors
Fuentes، نويسنده , , M. ?ngeles and Rodr?guez-Castillo، نويسنده , , Mar?a and Monge، نويسنده , , Miguel and Olmos، نويسنده , , M. Elena and L?pez-de-Luzuriaga، نويسنده , , Jose M. and Caballero، نويسنده , , Ana and Pérez، نويسنده , , Pedro J.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2011
Pages
4
From page
146
To page
149
Abstract
The complexes [Au2M2(C6F5)4(NCMe)2]n (M = Cu, 1; M = Ag, 2) have been tested as catalysts for the functionalization of alkanes by the carbene insertion methodology, using ethyl diazoacetate as the carbene source. Moderate to high conversions have been obtained. The observed selectivities seem to favor the proposal that the active metal for catalysis is the Cu/Ag center, the Au(C6F5)2 unit acting as a spectator ligand in both cases.
Keywords
C–H functionalization , Diazocompounds , Carbenes , Coinage metals
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2011
Journal title
INORGANICA CHIMICA ACTA
Record number
1329587
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