Title of article :
Synthesis and molecular structures of phenylacetylide triosmium clusters
Author/Authors :
Kizas، نويسنده , , Ol’ga A. and Ivanova، نويسنده , , Ekaterina A. and Godovikov، نويسنده , , Ivan A. and Dolgushin، نويسنده , , Fedor M.، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2011
Abstract :
The thermal decarbonylation of [Os3H(CO)10(μ,η2-CCPh)] (1) results in the complex [Os3H(CO)9(μ3,η2-CCPh)] (2) in a quantitative yield. The X-ray structural analysis has been performed for 1 and 2. The dependence of dynamic behavior of triosmium clusters on their structure is discussed.
Keywords :
Triosmium clusters , X-ray analysis , Stereochemical non-rigidity , Acetylenide ligand
Journal title :
INORGANICA CHIMICA ACTA
Journal title :
INORGANICA CHIMICA ACTA
