Author/Authors :
Kozitsyna، نويسنده , , Natalia Yu. and Nefedov، نويسنده , , Sergei E. and Klyagina، نويسنده , , Alla P. and Markov، نويسنده , , Alexander A. and Dobrokhotova، نويسنده , , Zhanna V. and Velikodny، نويسنده , , Yuri A. and Kochubey، نويسنده , , Dmitry I. and Zyubina، نويسنده , , Tatiana S. and Gekhman، نويسنده , , Alexander E. and Vargaftik، نويسنده , , Michael N. and Moiseev، نويسنده ,
Abstract :
The reaction between Pd3(OOCMe)6 and Ag2(OOCMe)2 afforded the first palladium–silver heterometallic acetate-bridged complex PdII[(μ-OOCMe)2AgI(HOOCMe)2]2 (1). The molecular geometry and electronic structure of 1 were studied by single-crystal XRD and quantum-chemical DFT calculations. Thermal transformations of 1 in vacuo and under Ar, H2 produced PdAg alloy nanoparticles characterized with powder XRD and EXAFS.
Keywords :
silver , PALLADIUM , Thermal decomposition , Quantum-chemical analysis , X-ray structure , Heterometallic complexes
