Title of article
Bis(o-trifluoromethylphenyl)dithiophosphinic methyl ester
Author/Authors
Klaehn، نويسنده , , John R. and Peterman، نويسنده , , Dean R. and Harrup، نويسنده , , Mason K. and Luther، نويسنده , , Thomas A. and Daniels، نويسنده , , Lee M.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2011
Pages
4
From page
519
To page
522
Abstract
When bis(o-trifluoromethylphenyl)dithiophosphinic acid (1) is dissolved in methanol, crystals of bis(o-trifluoromethylphenyl)dithiophosphinic methyl ester (2) are formed. The structure of dithiophosphinic methyl ester (2) has been characterized via single-crystal X-ray diffraction and multinuclear NMR studies. Compound 2 is remarkable in that the dithiophosphinic (PS2) core is preserved during this transformation. The transformation to 2 suggests that the o-trifluoromethylphenyl groups on phosphorus assist in retaining the PS2 core, possibly by steric hindrance.
Keywords
characterization , Dithiophosphinic acid , Dithiophosphinic ester , X-ray crystal determination , Synthesis
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2011
Journal title
INORGANICA CHIMICA ACTA
Record number
1329701
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