Author/Authors :
Kushch، نويسنده , , Lyudmila A. and Sasnovskaya، نويسنده , , Valentina D. and Yagubskii، نويسنده , , Eduard B. and Khasanov، نويسنده , , Salavat S. and Simonov، نويسنده , , Sergey V. and Shibaeva، نويسنده , , Rimma P. and Korolev، نويسنده , , Alexander V. and Starichenko، نويسنده , , Denis V. and Anokhin، نويسنده , , Anatoly O. and Irkhin، نويسنده , , Valentin Yu. and Shva، نويسنده ,
Abstract :
The first heterometallic chain cluster {[Mn4(hmp)6(NO3)2FeNO(CN)5·4CH3CN}n (1) based on the [Mn4(hmp)6] SMM has been synthesized. 1 has one-dimensional chain structure: the [Mn4(hmp)6] units are linked via CN-groups of nitroprusside anions. Its magnetic and relaxation properties and low temperature IR spectra under light irradiation have been investigated. The ferromagnetic exchange constants have been calculated.
Keywords :
Single-chain magnets (SCMs) , One-dimensional chain , Jahn–Teller elongation , magnetic susceptibility , Single-molecule magnets (SMMs) , Photochromic FeNO(CN)5 anion
