Title of article
Two new mononuclear gold(I)–nitrogen [N,N′-di(2,6-methyl)phenylformamidine] complexes: Syntheses and crystal structures
Author/Authors
Melgarejo، نويسنده , , Doris Y. and Chiarella، نويسنده , , Gina M. and Fackler Jr.، نويسنده , , John P.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2011
Pages
6
From page
297
To page
302
Abstract
Two gold(I) mononuclear complexes have been prepared by reacting gold(I) tetrahydrothiophene with N,N′-di(2,6-methyl)phenylformamidine. The neutral complex [N,N′-di(2,6-methyl)phenylformamidine)–gold(I) chloride (C17H20AuClN2) (1), crystallizes in the triclinic group P 1 ¯ while the cationic [N,N′-di(2,6-methyl)phenylformamidine](tetrahydrothiophene)–gold(I) (C21H28AuN2S) (2) crystallizes with a nitrate anion in the monoclinic group P2(1)/n. Both compounds are good starting materials for synthetic gold chemistry.
Keywords
Mononuclear gold(I) compounds , Formamidine complexes , Sulfur-gold-nitrogen connection , Anion-dependant synthesis , Gold(I) nitrate complex
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2011
Journal title
INORGANICA CHIMICA ACTA
Record number
1330151
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