Electronic structure of free and doped actinides: N and Z dependences of energy levels and electronic structure parameters

Theoretical study of electronic structure of antinide ions and its dependence on N and Z are presented in this paper. The main 5fN and excited 5fNn′l′N′ configurations of actinides have been studied using Hartree–Fock–Pauli approximation. Results of calculations of radial integrals and the energy of X-ray lines for all 5f ions with electronic state AC+1−AC+4 show approximate dependence on N and Z. A square of N and cubic of Z are ewalized for the primary electronic parameters of the actinides. Theoretical values of radial integrals for free actinides and for ions in a cluster AC+n:[L]k are compared, too.