Title of article :
Structural characterisation of difluoro-boron chelates of quino[7,8-h]quinoline
Author/Authors :
Shaffer، نويسنده , , Karl J. and McLean، نويسنده , , Tracey M. and Waterland، نويسنده , , Mark R. and Wenzel، نويسنده , , Marco and Plieger، نويسنده , , Paul G.، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2012
Abstract :
We report a milder synthetic route for the compounds 4,9-dichloroquino[7,8-h]quinoline L1 and quino[7,8-h]quinoline L2 and we utilise these ligands in the synthesis of boron difluoride chelates. X-ray crystallographic analysis of L1, [HL1]BF4 and the coordinated structures of [BF2L1]BF4 and [BF2L2]BF4 reveal the flexible nature of the ligand.
Keywords :
Synthesis , Metalloid binding , Boron difluoride , Proton sponge , X-ray structure , 8-h]quinoline
Journal title :
INORGANICA CHIMICA ACTA
Journal title :
INORGANICA CHIMICA ACTA