Title of article
Iron piano-stool phosphine complexes for catalytic hydrosilylation reaction
Author/Authors
Zheng، نويسنده , , Jianxia and Misal Castro، نويسنده , , Luis C. and Roisnel، نويسنده , , Thierry and Darcel، نويسنده , , Christophe and Sortais، نويسنده , , Jean-Baptiste، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2012
Pages
7
From page
301
To page
307
Abstract
A family of six cyclopentadienyl–iron carbonyl complexes bearing phosphine ligands (PPh3, PMe2Ph and PCy3) with iodide or PF6 as a counter-anion were prepared and used as catalysts for the hydrosilylation of carbonyl derivatives. Aldehydes were reduced at 30 °C, using PMHS as the silane, whereas ketones were reduced at 70 °C using PhSiH3.
Keywords
ketones , Aldehydes , Iron , Reduction , Hydrosilylation
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2012
Journal title
INORGANICA CHIMICA ACTA
Record number
1330536
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