Title of article
Synthesis, crystal structure and VT-NMR study of cis-[PdCl2(CNC6H3Me2-2,6)(PPh3)]
Author/Authors
Mart?nez-Mart?nez، نويسنده , , Antonio Jes?s and Chicote، نويسنده , , Mar?a Teresa and Bautista، نويسنده , , Delia، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2012
Pages
4
From page
203
To page
206
Abstract
The complex cis-[PdCl2(CNC6H3Me2-2,6)(PPh3)] has been prepared and fully characterized. Its crystal structure has been determined showing the chloro ligands in cis-disposition. A VT-NMR study shows this complex to be in equilibrium with trans-[PdCl2(PPh3)2] and cis-[PdCl2(CNC6H3Me2-2,6)2]. The equilibrium is fast at room temperature but at −50 °C all three species are observed in solution in 10:1:1 M ratio. The activation parameters for this equilibrium have been calculated.
Keywords
Phosphine/isocyanide mixed ligand complex , Rearrangement equilibrium , VT-NMR study , Activation parameters
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2012
Journal title
INORGANICA CHIMICA ACTA
Record number
1330607
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