Title of article
Reactions of molybdenum oxo-thioclusters with [Re(CO)5Cl]
Author/Authors
Abramov، نويسنده , , P.A. and Yu Laricheva، نويسنده , , A. and Peresypkina، نويسنده , , E.V. and Mirzaeva، نويسنده , , I.V. and Moroz، نويسنده , , N.K. and Sokolov، نويسنده , , M.N.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2012
Pages
6
From page
7
To page
12
Abstract
Reduction of [Mo2O2(μ-S)2(H2O)6]2+ with [Re(CO)5Cl] in 2 М HCl at 160 °C produces condensation of binuclear clusters with the formation of the{Mo3(μ3-S)(μ-O)3}4+ species, which was isolated and structurally characterized as {[Mo3(μ3-S)(μ2-O)3(H2O)6Cl3]2CB[6]}Cl2·10.88H2O (2) (CB[6] = C36H36N24O12) and [Mo3(μ3-S)(μ2-O)3(acac)3(py)3]PF6·2C6H5CH3 (3). Reaction of [Mo3(μ3-S)(μ2-S)(μ2-O)2(H2O)9]4+ with [Re(CO)5Cl] produces cuboidal cluster [Mo4(μ3-S)4(H2O)12]5+.
Keywords
Oxo-thio clusters of molybdenum , X-ray analysis , quantum-chemical calculations
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2012
Journal title
INORGANICA CHIMICA ACTA
Record number
1330610
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