Title of article
Direct determination of zero-field splitting in Co(II) complexes by FAR infrared spectroscopy
Author/Authors
?ebov?، نويسنده , , M. and Bo?a، نويسنده , , R. and Dlh??، نويسنده , , ?. and Nemec، نويسنده , , I. and Pap?nkov?، نويسنده , , B. and Pavlik، نويسنده , , J. and Fuess، نويسنده , , H.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2012
Pages
9
From page
143
To page
151
Abstract
Three centrosymmetric, mononuclear cobalt(II) complexes possessing large zero-field splitting parameter D have been studied by means temperature-dependent FAR infrared spectroscopy. From 15 temperature-dependent absorption peaks referring to the transition between the six lowest crystal-field multiplets the value of the D-parameter has been directly read off. These data are comparable with those values extracted by fitting the magnetic susceptibility and magnetization data.
Keywords
zero-field splitting , Cobalt(II) complexes , Far infrared spectroscopy , magnetism
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2012
Journal title
INORGANICA CHIMICA ACTA
Record number
1330631
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