Author/Authors :
Morales-Verdejo، نويسنده , , César and Martinez، نويسنده , , Ivan and Mac-Leod Carey، نويسنده , , Desmond and Chavez، نويسنده , , Ivonne and Manr?quez، نويسنده , , Juan Manuel and Matioszek، نويسنده , , Dimitri and Saffon، نويسنده , , Nathalie and Castel، نويسنده , , Annie and Rivière، نويسنده , , Pierre and Molins، نويسنده , , Elies، نويسنده ,
Abstract :
Three heterobimetallic complexes LmM(s-Ic′)M′Ln (M = Fe,Ru or Mn; M′ = Ni) having the same Cp∗ nickel moiety and based on a polyalkyl-s-indacenyl spacer (s-Ic′ = 2,6-diethyl-4,8-dimethyl-s-indacenyl) were synthesized by reacting Cp∗Ni(acac) with the lithium derivative of the parent monometalated complex. All three compounds were fully characterized and shown to adopt a trans geometry by X-ray crystallography.
Keywords :
X-ray structures , Manganese s-indacenyl complex , Nikel indacenyl heterobimetallic complexes: Ni/Fe , Polyalkyl-s-indacene , Ni/RuNi/Mn
