Author/Authors :
Wang، نويسنده , , Bin and Xu، نويسنده , , Ling-Xiao and Meng، نويسنده , , Rui-Qi and Suo، نويسنده , , Lin and Li، نويسنده , , Bao and Wu، نويسنده , , Li-Xin and Bi، نويسنده , , Li-Hua، نويسنده ,
Abstract :
A new mixed-valence SbV/III containing vanadium-substituted polyoxotungstate Na10[{SbV(OH)3}2{VIVO(H2O)}2{SbIIIW9O33}2]·32H2O (1-Na) has been synthesized by routine synthetic reaction and characterized by IR, XPS, elemental analysis. The polyoxoanion [{SbV(OH)3}2{VIVO(H2O)}2{SbIIIW9O33}2]10− (1) consists of two trilacunary species β-B-SbIIIW9O33 connected by two VIVO(H2O) groups and two SbV(OH)3 units. The cyclic voltammetry and catalytic activity of 1-Na for the oxidation of n-hexadecane under green condition have been measured.
Keywords :
vanadium , Polyoxotungstate , Mixed-valance cluster , crystal structure , Antimony
