Thin La2Zr2O7 films made from a water-based solution

Thin films of La2Zr2O7 (LZO) are highly regarded as possible buffer layers in the coated conductor configuration. This report describes a new synthesis for thin crystalline LZO films, based on a largely water-based solution, mainly containing metal acetates, acetic acid and an organic amine-base: triethanolamine. Initially, a thin layer of amorphous material is deposited on the textured Ni-5 at%W substrate by means of dip-coating. Only by careful control of the thermal treatment can the layer be transformed into a crystalline layer. Important parameters in this respect are the heating rate and the dwell time. The amorphous gel is analysed by HR-TGA/DTA and HR-TEM. The textured layers are analysed by XRD, pole figures, RHEED, AFM and SEM.