Title of article
2D water layer enclathrated between Mn(II)–Ni(CN)4 coordination frameworks
Author/Authors
Ambarish Ray، نويسنده , , Indrani Bhowmick، نويسنده , , William S. Sheldrick، نويسنده , , Atish Dipankar Jana، نويسنده , , Mahammed Ali، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2009
Pages
5
From page
2608
To page
2612
Abstract
A [Ni(CN)4]2−-based two-dimensional Mn(II) coordination polymer {Mn(H2O)2[NiCN]4·4H2O}, in which the coordination layers are stacked on top of each other sandwiching 2D water layer of boat-shaped hexagonal water clusters has been synthesized. The complex exhibits high thermal decomposition temperature and reversible water absorption, which were clearly demonstrated by thermal and PXRD studies on the parent and rehydrated complex after dehydration.
Keywords
2D Coordination polymer , 2D ice layer , High thermal stability , Boat-shaped hexagonal water clusters , Reversible water adsorption
Journal title
JOURNAL OF SOLID STATE CHEMISTRY
Serial Year
2009
Journal title
JOURNAL OF SOLID STATE CHEMISTRY
Record number
1334114
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