Phase relations and structural features in the system Ni–Zn–B

Phase relations for the system Ni–Zn–B have been established in the isothermal section at 800 °C based on X-ray powder diffraction and electron microprobe analyses of about 60 samples, which have been prepared by hot pressing of pre-annealed powder compacts of arc-melted master alloys NixBy and Zn-filings. Six ternary compounds (labeled τ 1 to τ 6) were found to exist, which in some cases exhibit considerable mutual solid solubilities mostly as an exchange of Ni–Zn at constant B-content, but in the case of the so-called τ -phase τ 1-(Ni1−xZnx)21[Zn1−y−z□y(B4)z]2B6 (0.07≤x ≤0.11, 0.07≤y ≤0.53, 0≤z ≤0.3) also with Zn/B substitution. Single crystal X-ray data analysis for the composition x =0.07, y =0.125, z =0.30, and a =1.05800(3) nm confirmed the Cr23C6 type with space group View the MathML sourceFm3¯m, but revealed partial replacement of Zn-atoms by B4-tetrahedra (RF=0.014). Whereas Ni/Zn exchange (at constant B-content) ranges at about 4–5 at% for τ4-Ni3ZnB2 and τ5-Ni48Zn32B20, it is below 3 at% for τ2-Ni12ZnB8−x (x=0.43), τ3-Ni21Zn2B20 and τ6-Ni47Zn23B30. The crystal structures of τ2-Ni12ZnB8−x (x=0.43; Ni12AlB8 type), τ3-Ni21Zn2B20 (own type) and τ4-Ni3ZnB2 (own type) have been determined in our foregoing paper [8]. Due to the non-availability of suitable single crystals, the crystal structures of τ5-Ni48Zn32B20 (body-centered orthorhombic; a=1.6(2) nm, b=0.63(7) nm, and c=0.27(0) nm, determined from TEM) and of τ6-Ni47Zn23B30 have not been elucidated yet. Phase equilibria at 800 °C are dominated by a large three-phase field (βB)+Ni2Zn11+τ3, as practically all ternary compounds form at compositions with less than about 50 at% Ni. Furthermore, precise data on atom site distribution and positional parameters have been provided from X-ray single crystal refinements for Ni-borides, for which crystal structures hitherto have only been derived from X-ray diffraction photographs: o-Ni4B3−x (x=0.19; Pnma, a=1.9665(4) nm, b=0.29852(1) nm, c=0.65750(2) nm; RF=0.015) and m-Ni4B3 (C2/c, a=0.64356(3) nm, b=0.48867(3) nm, c=0.78267(3) nm, β=103.288(3)°, RF=0.021).