Improvement of the model for surface process of tritium release from lithium oxide

Among the various tritium transport processes in lithium ceramics, the importance and the detailed mechanism of surface reactions remain to be elucidated. The dynamic adsorption and desorption model for tritium desorption from lithium ceramics, especially Li2O was constructed. From the experimental results, it was considered that both H2 and H2O are dissociatively adsorbed on Li2O and generate OH− on the surface. In the first model developed in 1994, it was assumed that either the dissociative adsorption of H2 or H2O on Li2O generates two OH− on the surface. However, recent calculation results show that the generation of one OH− and one H− is more stable than that of two OH−s by the dissociative adsorption of H2. Therefore, assumption of H2 adsorption and desorption in the first model is improved and the tritium release behavior from Li2O surface is evaluated again by using the improved model. The tritium residence time on the Li2O surface is calculated using the improved model, and the results are compared with the experimental results. The calculation results using the improved model agree well with the experimental results than those using the first model.