Title of article :
Synthesis and characterization of poly(diphenylacetylenes) containing both hydroxy and halogen/alkyl groups as gas separation membranes
Author/Authors :
Yanming Hu، نويسنده , , Toshikazu Sakaguchi، نويسنده , , Masashi Shiotsuki، نويسنده , , Fumio Sanda، نويسنده , , Toshio Masuda، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2006
Pages :
8
From page :
412
To page :
419
Abstract :
Diphenylacetylene containing siloxy and halogen/alkyl groups (P-t-BuMe2SiO-C6H4Ctriple bond; length of mdashCC6H4-p-X, X = Cl, Br, I, Me, Et, 1b–f, respectively) were polymerized with TaCl5-n-Bu4Sn catalyst to provide high molecular weight polymers (2b–f) in good yields. These polymers afforded tough free-standing membranes by casting from toluene solution. Desilylation of these siloxy-containing polymer membranes was carried out with trifluoroacetic acid to give membranes of poly(diphenylacetylenes) having hydroxy and halogen/alkyl groups (3b–f). Polymers 2b–f were soluble in nonpolar solvents such as cyclohexane, toluene, and THF, while polymers 3b–f were insoluble in these solvents. The oxygen permeability coefficients (image) of membranes 2b–f and 3b–f were in the range of 140–280 and 12–190 barrers, respectively. The gas permeabilities of most membranes (2b–e and 3b–f) were higher than those of the corresponding polymer membranes without halogen/alkyl substituents (2a and 3a), suggesting that introduction of small spherical groups (halogen and methyl) into the polymers 2a and 3a enhances gas permeability. The incorporation of halogen atoms into the present membranes was more effective to improve gas permeability than methyl and ethyl groups. The points of 3b–e in the image versus image plots were located obviously above Robesonʹs upper bound.
Keywords :
desilylation , Poly(diphenylacetylene) , membrane , Gas permeability
Journal title :
Journal of Membrane Science
Serial Year :
2006
Journal title :
Journal of Membrane Science
Record number :
1352851
Link To Document :
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