Title of article :
Gel polymer electrolytes based on active PVDF separator for lithium ion battery. I: Preparation and property of PVDF/poly(dimethylsiloxane) blending membrane
Author/Authors :
Hao Li، نويسنده , , Yue Ming Chen، نويسنده , , Xiao-Ting Ma، نويسنده , , Jun-Li Shi، نويسنده , , Bao-Ku Zhu، نويسنده , , Liping Zhu، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2011
Pages :
6
From page :
397
To page :
402
Abstract :
This work explores the “active” separator that can be activated into gel or polymer electrolyte membrane. The active nature and easier processing property make the separator more applicable in assembling batteries. To improve the activeness of PVDF based separators, the poly(dimethylsiloxane) (PDMS) was blended into porous PVDF membrane matrix via a typical phase inversion route. By measuring the composition, morphology, ion conductivity, and so on, the work studies the influence of PDMS on structure and properties of blending separators. Compared with pure PVDF membrane having comparable porous structure, the adoption of PDMS not only decreases the crystallinity and increases the breaking elongation efficiently, but also enhances the stability of entrapped liquid electrolyte and ion conductivity. For separators with PVDF/PDMS mass ratio in 7/3, the liquid electrolyte uptake reached 250 wt% and ion conductivity of formed gel electrolyte membrane was 1.17 × 10−3 S cm−1, which was acceptable for high voltage lithium ion batteries.
Keywords :
Lithium battery , Poly(vinylidene fluoride) , Poly(dimethyl siloxane) , Porous separator , Ion conductivity
Journal title :
Journal of Membrane Science
Serial Year :
2011
Journal title :
Journal of Membrane Science
Record number :
1356504
Link To Document :
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