Stainless steel containers for the storage of low and medium level radioactive waste

Corrosion investigations have been performed on the austenitic structural steel AISI 304L, in comparison with the structural steel AISI 316L, in an aerated and a de-aerated solution, which was leached from low and medium level radioactive waste. On the basis of measured potentio-dynamic anodic polarization curves and the results of cyclic polarization tests, it was found that both types of steel, as well as the corresponding welds, had a high pitting potential and a high protective potential, which means that they have a strong tendency to form a compact and corrosion-resistant passive film. The repassivation capability of both types of steel prevents the occurrence of stress corrosion cracking at the level of concentration of chloride ions which corresponds to the described type of waste, whereas absorbed atomic hydrogen does not reduce toughness or cause hydrogen embrittlement. The results of the research work confirmed that it is possible to use AISI 304L structural steel for the construction of containers for the temporary, 30-year storage of low and medium level radioactive waste.