Title of article :
Oxygen permeation and oxidation states of transition metals in (Fe, Nb)-doped BaCoO3 − δ perovskites
Author/Authors :
Jianxin Yi، نويسنده , , Jochen Brendt، نويسنده , , Michael Schroeder، نويسنده , , Chunhui Luo Manfred Martin، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2012
Pages :
7
From page :
17
To page :
23
Abstract :
The influence of cation substitution on the transition metal oxidation states, oxygen nonstoichiometry and oxygen transport properties of Ba(Co, Fe, Nb)O3 − δ perovskites was investigated with room temperature XRD, X-ray absorption near edge structure and high temperature oxygen permeation measurements. Results show that substitution of Fe for Co is accompanied by a decrease in the lattice constant, whereas Nb substitution leads to the opposite trend. With increasing Fe and/or Nb content, the oxygen permeation flux decreases, whereas the apparent activation energy of the oxygen permeation increases. The oxidation state of Co is smaller than +3 and susceptible to the variation of cation composition. In contrast, the oxidation states of Fe and Nb are larger than +3 and close to +5, respectively, and almost independent of the composition. The influence of Fe and Nb contents on the oxygen transport properties is discussed in terms of the oxygen stoichiometry and metal–oxygen bonding.
Keywords :
Oxidation state , X-ray absorption , Mixed conductor , Oxygen separation , Perovskite
Journal title :
Journal of Membrane Science
Serial Year :
2012
Journal title :
Journal of Membrane Science
Record number :
1357100
Link To Document :
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