Title of article :
Synthesis and reactions of B-vinylcarboranes
Author/Authors :
Kuanysh Z. Kabytaev، نويسنده , , Alexander V. Safronov، نويسنده , , Satish S. Jalisatgi، نويسنده , , M. Frederick Hawthorne، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2014
Abstract :
B-Vinylcarboranes were prepared via the palladium-catalyzed cross-coupling of iodocarboranes with vinylmagnesium bromide. Further transformations of the 9-vinyl-1,2-dicarba-closo-dodecaborane side chain yielded bromination, epoxidation, dihydroxylation, oxidative cleavage, radical sulfur addition, and hydroboration/oxidation products.
Keywords :
Electrophilic addition , radical reaction , Cross-coupling , Carboranes , Oxidation
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
