• Title of article

    Selectivity in alkynylation: the reaction between Ru2(LL)4Cl and Me3SnCCR (LL=2-anilinopyridine, 2-chloro- and 2-bromo-oxypyridine)

  • Author/Authors

    F. Albert Cotton، نويسنده , , Salah-Eddine Stiriba، نويسنده , , Alexandre Yokochi، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2000
  • Pages
    3
  • From page
    300
  • To page
    302
  • Abstract
    The reaction via a Pd(II)/CuI catalyst of phenylethynyl(trimethyl)stannane (Me3SnCCPh) with Ru2(chp)4Cl, Ru2(bhp)4Cl and Ru2(ap)4Cl gave the organometallic terminal alkynes Ru2(chp)4CCPh (1), Ru2(bhp)4CCPh (2) and Ru2(ap)4CCPh (3), respectively in 80–85% yields, without an attack on other functionalities.
  • Keywords
    Alkynyl complexes , Coupling reaction , Diruthenium , Oxopyridine
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    2000
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1369784