Title of article :
Reaction of nickelocene with 1,3-dimesitylimidazolium chloride
Author/Authors :
Colin D Abernethy، نويسنده , , Alan H، نويسنده , , Cowley، نويسنده , , Richard A Jones، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2000
Abstract :
Treatment of nickelocene with 1,3-dimesitylimidazolium chloride affords the corresponding carbene complex, (η5-C5H5)NiCl(carbene) (5). The structure of 5 was determined by X-ray crystallography. The distorted trigonal planar nickel atom is attached to an η5-Cp, a carbene, and a chloride ligand. Compound 5 reacts with MeLi to afford (η5-C5H5)Ni(Me)(carbene).
Keywords :
nickel , Imidazolium , Cyclopentadienyl , carbene complex , Chlorine
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
