Title of article :
The synthesis and structural characterization of C3 symmetry “star-like” cluster [{Os3(μ-H)(CO)10}3{1,3,5-(μ-SCH2)3C6H3}]
Author/Authors :
Gloria S?nchez-Cabrera، نويسنده , , Francisco J. Zuno-Cruz، نويسنده , , Heraclio L?pez-Ruiz، نويسنده , , Mar?a J. Rosales-Hoz، نويسنده , , Marco A. Leyva-Ramirez، نويسنده , , José A. Rodr?guez، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2014
Abstract :
The cluster [{Os3(μ-H)(CO)10}3{1,3,5-(μ-SCH2)3C6H3}] has been prepared by the reaction of [Os3(CO)10(NCMe)2] with 1,3,5-tris(mercaptomethyl)benzene under mild conditions; the cluster has been fully characterized by IR, NMR spectroscopy, HR-MS, X-ray crystallography and its redox behavior is also described.
Keywords :
Thiolato complexes , crystal structure , C3 symmetry , Cyclic voltammetry , Osmium clusters
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
