Title of article :
Photolysis of 7,8-digermabicyclo[2.2.2]octadiene. The investigation of the elementary stages by means of 1H CIDNP and laser pulse photolysis
Author/Authors :
M.B. Taraban، نويسنده , , O.S Volkova، نويسنده , , V.F. Plyusnin، نويسنده , , Yu.V Ivanov، نويسنده , , T.V. Leshina، نويسنده , , M.P Egorov، نويسنده , , O.M Nefedov، نويسنده , , T Kayamori، نويسنده , , K Mochida، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2000
Abstract :
Photolysis of 7,8-digermabicyclo[2.2.2]octadiene (I) was studied by means of 1H-CIDNP and laser pulse photolysis techniques. It was found that photodecomposition of I occurs via germanium-centered 1,6-biradical species. 1,4-Diphenylnaphthalene and tetramethyldigermene are the primary products of the photolytic reaction.
Keywords :
Germanium , Digermabicyclooctadiene , Tetramethyldigermene , Dimethylgermylene , Laser flash photolysis , CIDNP
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
