• Title of article

    Aurophilic association in endo-dicyclopentadienechlorogold(I)

  • Author/Authors

    Mikael H?kansson*، نويسنده , , Henrik Eriksson، نويسنده , , Susan Jagner، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2000
  • Pages
    4
  • From page
    133
  • To page
    136
  • Abstract
    The complex between endo-dicyclopentadiene and gold(I) chloride has been prepared by a substitution reaction in dichloromethane, whereby carbon monoxide in dissolved [AuCl(CO)] has been displaced by the endo-dicyclopentadiene ligand. This ligand is η2-bonded to gold(I) via the CC bond in the norbornene ring. Crystallographic studies show that the [AuCl(C10H12)] moiety undergoes aurophilic association to form a [{AuCl(C10H12)}2] dimer, in which the AuAu distance is 3.4282(8) Å.
  • Keywords
    Gold(I) , Aurophilic , endo-Dicyclopentadiene , crystal structure , Infrared spectroscopy
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    2000
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1370704

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1370704