• Title of article

    The first structurally characterised oligosilylmagnesium compound

  • Author/Authors

    James D. Farwell، نويسنده , , Michael F. Lappert، نويسنده , , Christoph Marschner، نويسنده , , Christine Strissel، نويسنده , , T. Don Tilley، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2000
  • Pages
    4
  • From page
    185
  • To page
    188
  • Abstract
    The crystalline magnesium compounds Mg[Si(SiMe3)3]2(thf)2 (1) and MgBr[Si(SiMe3)3](thf)2 (2) are obtained in high yield from MgBr2 and the Li or K sisyl in appropriate stoichiometry in Et2O or thf; NMR spectra and X-ray crystal data for 1 and 2 confirm their structures; for 1: MgSi 2.682(2) Å, SiMgSi′ 131.19(15)°.
  • Keywords
    Tris(trimethylsilyl)silyl (? sisyl) , Magnesium , A sisyl-Grignard reagent
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    2000
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1370750

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1370750